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What's the advanced oxidation processes (AOPs)?
发布日期: 2024-10-31
阅读数: 34

What's the advanced oxidation processes (AOPs)?


Advanced Oxidation Processes (AOPs) are a set of chemical treatment methods used to degrade and remove organic and inorganic pollutants from water and wastewater. AOPs are characterized by the generation of highly reactive hydroxyl radicals (•OH), which are powerful oxidizing agents capable of breaking down a wide range of contaminants into smaller, less harmful molecules. Some common AOPs include:

 

1.Fenton Reaction: Involves the addition of hydrogen peroxide (H2O2) to water containing ferrous iron (Fe^2+) catalyst. The reaction produces hydroxyl radicals (OH) which oxidize organic pollutants. The overall reaction can be represented as:

 

Fe^2+ + H2O2 Fe^3+ + OH + OH^-

 

2.Photo-Fenton Reaction: Similar to the Fenton reaction, but with the addition of UV or visible light. Light activation enhances the generation of hydroxyl radicals, increasing the efficiency of pollutant degradation.

 

3.Ozone (O3) + Hydrogen Peroxide (H2O2): Ozone and hydrogen peroxide are combined to generate hydroxyl radicals through several pathways, including the decomposition of ozone to form hydroxyl radicals and the reaction of ozone with hydrogen peroxide to form hydroperoxyl radicals (HO2), which subsequently decompose to form hydroxyl radicals.

 

4.Ultraviolet (UV) Photolysis of Hydrogen Peroxide (UV/H2O2): UV light is used to photolyze hydrogen peroxide, generating hydroxyl radicals. This process is particularly effective for the degradation of organic pollutants in water.

 

5.Electrochemical Advanced Oxidation Processes (EAOPs): Involve the generation of hydroxyl radicals through electrochemical reactions, such as electrolysis of water or the oxidation of water at an electrode surface. Examples include electro-Fenton and electrochemical oxidation processes.

 

AOPs offer several advantages for water treatment, including the ability to degrade recalcitrant pollutants, operate under mild conditions (ambient temperature and pressure), and produce minimal harmful byproducts. They are particularly useful for the removal of emerging contaminants, pharmaceuticals, pesticides, and industrial chemicals that are not effectively treated by conventional water treatment methods. However, AOPs can be energy-intensive and may require careful optimization of process parameters to achieve desired treatment outcomes.



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